王凯，汉族，湖南汨罗人。博士，教授。
电子邮箱：kaiwang@glut.edu.cn
一、教育工作经历
2016.09至今：桂林理工大学，化学与生物工程学院任教。
2009.07-2016.07：桂林师范高等专科学校，化学与药学系任教。
2011.09-2015.06：南京大学，化学化工学院，无机化学专业，获理学博士学位。
2006.09-2009.06：广西师范大学，化学与药学学院，有机化学专业，获理学硕士学位。
2002.09-2006.06：广西师范大学，化学与药学学院，化学专业，获理学学士学位。
二、教学工作
主要承担《无机化学》、《普通化学》、《大学化学》等本科生课程，《单晶结构解析》等研究生课程。主持广西高等教育本科教学改革工程项目1项，参编《普通化学》与《有机化学化学》教材2部。
教学/指导学生获奖：
1）广西高校大学生化学实验技能竞赛“优秀教练员”。
2）第八届广西高校青年教师教学竞赛三等奖。
3）桂林理工大学第十八届“十佳授课教师”。
4）指导本科生获“挑战杯”广西大学生课外学术科技作品竞赛特等奖1项、二等奖1项。
5）指导本科生获广西高校大学生化学化工类论文及设计竞赛一等奖1项、二等奖3项。
6）指导本科生获广西高校大学生化学实验技能竞赛一等奖5项，二等奖2项，三等奖3项。
7）指导硕士研究生林超斌、郭柯柯获广西青年学术年会论文一等奖1项。
8）指导郭柯柯硕士学位论文获评2019年桂林理工大学优秀研究生学位论文。
9）指导苏森达硕士学位论文获评2019年桂林理工大学优秀研究生学位论文。
10）指导罗学晶硕士学位论文获评2022年桂林理工大学优秀研究生学位论文。
11）指导朱孟孟硕士学位论文获评2023年桂林理工大学优秀研究生学位论文。
12）指导蔡展婷硕士学位论文获评2024年桂林理工大学优秀研究生学位论文。
三、科研工作
主要从事稀土分子基材料的设计合成及其磁性、光响应性与光催化活性研究。主持国家自然科学基金2项、广西自然科学基金3项、广西高校科研项目1项；作为第一作者或通讯作者已在Chinese Chem. Lett.、Chem. Commum.、Inorg. Chem.、J Org. Chem.、Cryst. Growth Des.、Dalton Trans.、Adv. Synth. Catal.等重要学术刊物上发表SCI论文30余篇，获授权专利6件，参编学术专著1部；曾获2012年广西自然科学奖三等奖1项。
主持科研项目：
1）国家自然科学基金：含主客体型π-π供受体对的光响应性稀土分子磁体研究。
2）国家自然科学基金：稀土单分子磁体中单离子磁各向异性与磁交换作用协同的机制与调控研究。
3）广西自然科学基金：光刺激响应性Dy基分子磁体的设计合成与响应机制研究。
4）广西自然科学基金：双核稀土单分子磁体的合成、弛豫机理与磁构关系研究。
5）广西自然科学基金：配体调控的Gd基配合物合成及其磁制冷性质研究。
研究论文：
1）Qin, Y.; Wu, C. E.; Li, C. J.; Cai, Z. T.; Hu, B.; Wang, Q. B.; Chen, Z. L.*; Liang, F. P.*; Wang, K.* Supermolecular aggregates of mononuclear and asymmetric dinuclear dysprosium single-molecule magnets assembled by intermolecular hydrogen bonds. Cryst. Growth Des., 2024, 24, 6148−6157.
2）Liu, Y.; Guo, K. K.; Wu, J. L.; Tang, S.*; Teng, Q. H.*; Liang, F. P.; Wang, K.* From Dy-chain to Dy-dimer: significant structural variation induced only by counter cations and slow magnetic relaxation behaviors. J Mol. Struct., 2024, 1316, 139038.
3）Cai, Z. T.; Peng, S.; Gao, J. F.; Zhu, Z. R.*; Liang, F. P.*, Wang, K.* Spontaneous resolution and magnetic properties of lanthanide metal organic frameworks based on oxydiacetate. Polyhedron, 2024, 260, 117104.
4）Huang, F. P.; Qin, W. J.; Pan, X. Y.; Yang, K.; Wang, K.*; Teng, Q. H.* Visible-light induced chemodivergent synthesis of tetracyclic quinazolinones and 3-iminoisoindoliones via substrate control strategy. J Org. Chem., 2024, 89, 4395–4405.
5）Pan, X. Y.; Sun, G. X.; Huang, F. P.; Qin, W. J.; Teng, Q. H.*; Wang, K.* Photogenerated chlorine radical activated C(sp3)–H bonds of alkylbenzenes to access quinazolinones. Org. Biomol. Chem., 2024, 22, 2968–2973.
6）Peng S.; Ouyang, X. M.; Wang, Y. H.; Teng, Q. H.*; Li, Y.; Zhang, X. Q.; Hu, Z. B.; Wang, K.*; Liang, F. P.* In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases, Chinese Chem. Lett., 2023, 34, 108044.
7）Luo, X. J.; Liu, Y.; Pan, H. D.; Peng, S.; Hu, Z. B.*; Teng, Q. H.; Li, Y.; Liang, F. P.*, Wang, K.* Photoresponsive magnetic relaxation behavior of a highly stable π···π interaction-stacked framework based on a DyIII single-ion magnet. Cryst. Growth Des., 2023, 23, 4825–4835.
8）Chen, J. H.; Peng, S.; Pan, H. D.; Wu, C. E.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Liang, F. P.*; Wang, K.* Dysprosium clusters from 3-ethoxysalicylidene terminal-decorated acylhydrazone ligands: in situ ligand-transformation-assisted assembly and zero field single-molecule magnet behaviors. Cryst. Growth Des., 2023, 23, 4927–4938.
9）Teng, Q. H.*; Sun, G. X.; Huang, F. P.; Wang, K.*; Liang, F. P.* Visible-light induced cerium-catalyzed N-demethylation of N-methyl amides under air conditions. Adv. Synth. Catal., 2023, 365, 307–311.
10）Liu, L.; Yang, P. P.; Qiu, Z. H.*; Wang, K.*; Liu, D. C.; Liang, Y. N.; Hu, H. C.; Zou, H. H.; Liang, F. P.; Chen, Z. L*. Russian doll-like 3d-4f cluster wheels with slow relaxation of magnetization. Molecules, 2023, 28, 5906.
11）Wang, Y. H.; Qin, Y.; Tang, S.; Teng, Q. H.*; Zhu, M. M.; Peng, S.; Wang, K.*; Liang, F. P.* Asymmetric {Dy4} metallogrid and double-layered {Dy8} cage clusters from carboxylic decorated o-vanillin schiff bases: syntheses, topological variation, and single molecule magnet behaviors. New J Chem., 2023, 47, 2052–2059.
12）Zhu, M. M.; Pan, H. D.; Teng, Q. H.*; Liang, F. P.*, Wang, K.* Slow magnetic relaxation behavior of a {Dy2} complex based on large π-conjugated bridging ligand. Polyhedron, 2023, 232, 1116271.
13）Pan, H. Dong.; Wu, C. E., Chen, J. H.; Li, Y.; Zhang, X. Q.; Teng, Q. H.*; Wang, K.*; Liang, F. P.* A pair of 2D MOFs based on [Tm2] secondary building units: syntheses, structural variation and magnetic properties. J Clust. Sci., 2023, 34, 1769–1776.
14）Kong, F. Y.; Han, H. Z.; Huang, S. X.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Zhu, L.*; Wang, K.*; Liang, F. P.* A pair of chiral dysprosium single-ion magnets with 2,6-bis[(4S/4R)4-phenyl-2-oxazolinyl]pyridine and hexafluoroacetylacetonate ligands. Russ. J. Coordin. Chem., 2022, 48, 667–674.
15）Teng, Q. H.; Sun, G. X.; Luo, S. Y.; Wang, K.*; Liang, F. P.* Design, syntheses and antitumor activities evaluation of 1,5-diaryl substituted pyrazole secnidazole ester derivatives. J Heterocyclic Chem., 2021, 58, 1656–1664.
16）Xu, F.; Luo, X. J.; Wu, C. E.; Liao, B. Y.; Wang, K.*; Liang, F. P.* A quasi-liner {MnIIDyIIIMnII} cluster featuring in situ Schiff base ligand transformation. J Clust. Sci., 2021, 32, 1411–1418.
17）Huang, S. X.; Xu, F.; Qi, S. J.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Luo, S. Y.*; Liang, F. P.* A double-layered {Cu9} nanocage with diacylhydrazine: synthesis, structure and magnetic properties. J Clust. Sci., 2021, 32, 765–772.
18）Lin, C. B.; Guo, K. K.; Guo, W. X.; Wang, Y. H.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* Rationally designing MOFs based on [Ln2] magnetic building blocks utilizing 2-hydroxyisophthalate and fine-tuning the magnetic properties of Dy analogues by terminal coordinated solvents. Inorg. Chem., 2020, 59, 16924−16935.
19）Su, S. D.; Li, J. X.; Xu, F.; Wang, C. X.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* DyIII single-molecule magnets from ligands incorporating both amine and acylhydrazine Schiff base groups: the centrosymmetric {Dy2} displaying dual magnetic relaxation behaviors. Dalton Trans., 2020, 49, 15739–15749.
20）Su, S. D.; Ou-Yang, X. M.; Guo, K. K.; Lin, Q. M.; Li, Y.; Wang, K.*; Luo, S. Y.*; Liang, F. P.* Synthesis, structure and magnetic properties of a Fe(III) [24-azaMC-8] azametallacrown nanocluster with diacylhydrazine ligand. J Clust. Sci., 2019, 30, 863–868.
21）Guo, K. K.; Su, S. D.; Shen, Y. L.; Wang, K.*; Li, Y.; Zhang, X. Q.; Li, B.*; Zou, H. H.; Liang, F. P.* A [Cu3] cluster-based chain featuring linkages of acylhydrazone N–N Single Bonds and Cl- ions: synthesis, structure and magnetic properties. J Clust. Sci., 2019, 30, 219–224.
22）Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, S. H.; Li, Y.; Zhang, X. Q.; Sun, W. Y.; Liang, F. P.* Diacylhydrazone assembled {Ln11} nanoclusters featuring a “double-boats conformation” topology: synthesis, structures and magnetism. Dalton Trans., 2018, 47, 2337–2343.
23）Wang, K.; Tang S.; Hu, Z. B.; Zou, H. H.; Wang, X. L.; Zhang, S. H.; Li, Y.; Chen, Z. L.; Liang, F. P.* A family of 3d metal clusters based on N–N single bonds bridged quasi-linear trinuclear cores: the Mn analogue displaying single-molecule magnet behavior. RSC Adv., 2018, 8, 6218–6224.
24）Wang, K.; Chen, Z. L.; Zou, H. H.; Li, Y.; Liang, F. P.* A series of 3d complexes from in-situ reactions of a flexible diacylhydrazine ligand: synthesis, structures and magnetic properties. Transit. Metal Chem., 2017, 42, 17–23.
25）Wang, K.; Chen, Z. L.; Zou, H. H.; Hu, K.; Li, H. Y.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A single-stranded {Gd18} nanowheel with symmetric polydentate diacylhydrazone ligand. Chem. Commun., 2016, 52, 8297−8300.
26）Wang, K.; Huang, X. K.; Zhu. L.; Chen, Z. L.; Liang, F. P.* A chain cadmium(II) coordination polymer with diacylhydrazide: synthesis, crystal structure and luminescent property. Chin. J. Struct. Chem., 2016, 35, 1912-1919.
27）Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* Two types of Cu-Ln heterometallic coordination polymers with 2-hydroxyl isophthalate: syntheses, structures and magnetic properties. Cryst. Growth Des., 2015, 15, 2883−2890.
28）Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* One-dimensional Co(II)/Ni(II) complexes of 2−hydroxyl isophthalate: structures and magnetic properties. J. Solid State Chem., 2015, 226, 36−41.
29）Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescent properties. Dalton Trans., 2014, 43, 12989−12995.
30）Wang, K.; Liu, X. X.; Yi, X. H.; Wang, H. S.; Zhang, Y.; Pan, Y. M.* Synthesis and metal ion binding activity of methyl 12-amino-13-nitro-7-oxo dehydrodeisopropylabietate derivatives. Med. Chem. Res., 2012, 21, 2494−2500.
31）Wang, K.; Zhang, Y.; Ekunwe, S. I. N.; Yi, X. H.; Liu, X. X.; Wang, H. S.; Pan, Y. M.* Antioxidant activities and inhibition effect of esculetin from Cortex Fraxini on the growth of human colon carcinoma (HT-29) cells. Med. Chem. Res., 2011, 20, 968–974.
32）Wang, K.; Pan, Y. M.*; Wang, H. S.; Zhang, Y.; Lei, Q.; Zhu, Z. R.; Li, H. Y.; Liang, M. Antioxidant activities of Liquidambar formosana Hance leaf extracts. Med. Chem. Res., 2010, 19, 166−176.
授权专利：
1）王凯，王亦寒，徐凡，滕青湖；一种镝-镧异稀土配位聚合物及其分步合成方法与应用；申请(专利)号：CN202211545653.9；授权公告号：CN115850716B。
2）王凯，罗学晶，滕青湖，梁福沛；一种基于不对称双核镝配合物的单分子磁体及其制备方法；申请(专利)号：CN202210213118.7；授权公告号：CN114573609B。
3）王凯，朱孟孟，滕青湖，梁福沛；一种基于双水杨醛缩氮氧吡啶-2,6-二甲酰腙的稀土单离子磁体及其制备方法；申请(专利)号：CN202111510152.2；授权公告号：CN114133407B。
4）王凯，王亦寒，秦雨，梁福沛；一种有序封装四硫富瓦烯客体的光刺激响应性铕基金属有机框架；申请(专利)号：CN202211543450.6；授权公告号：CN115746326B。
5）王凯，罗学晶，滕青湖，梁福沛；一种兼具高稳定性与光刺激响应性的镝基单离子磁体超分子框架及其合成方法；申请(专利)号：CN202210262448.5；授权公告号：CN114835909B。
6）王凯，郭柯柯，黄生学，梁福沛；一种具有磁制冷效应的二维钆基化合物及其制备方法；申请(专利)号：CN201810861783.0；授权公告号：CN109134874B。
