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张淑华 教授

来源: 作者: 发布时间:2015-10-14 浏览次数:

张淑华教授

 

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张淑华,男,汉族,1970年生,湖南邵阳人。化学与生物工程学院副院长。1993年毕业于湖南邵阳学院化学工程专业,20026月获广西师范大学无机化学专业硕士学位,20093月获南京大学无机化学理学获博士学位。2002年起在桂林工学院工作,2006年破格晋升为副研究员,2007年聘为化学工程与工艺专业硕士生导师,2009年晋升为教授。20123-20128月,英国Middlexsex University大学高级访问学者。201310-201410月,San Jose State University访问学者。广西高校优秀人才项目获得者,广西第一届优秀青年骨干教师项目获得者。2017年聘为材料科学与工程博士生导师。

张淑华教授长期从事功能材料的设计、合成及性能探索工作。在金属簇合物、磁性功能配合物的系统研究中构筑了近200个结构新颖的化合物,均拿到单晶衍射结构数据。作为负责人承担了国家自然科学基金,广西自然科学基金等项目10余项。申请国家发明专利192项,已获得授权22项。作为主要作者发表论文160余篇,SCI收录130篇,SCI引用超过500次;受邀成为Dalton Transaction, Arabian Journal of Chemistry, Supramolecular Chemistry, Journal of Solid State Chemistry, Journal of Coordination Chemistry, Journal of Molecular Structure, Journal of Cluster Science, Z. Anorg. Allg. Chem.等国际期刊及无机化学,结构化学等国内期刊的审稿人。

2013年或广西自然科学三等奖1项(获奖证书号:2013-Z-3-003-01),2006年获广西科学技术进步奖三等奖1项(证书号:2006-3-071-03)。已主讲4门研究生课程:《固体无机化学》、《功能有机材料》、《化工测试技术》、《化工论文阅读与写作》;讲授本科生课程有《普通化学》、《无机化学》、《有机化学》、《化学工程基础》、《化工制图》、《化工设备与过程开发》等。指导近40名本科毕业论文;指导硕士生18名(已毕业13名),其中有9名考上重点大学博士生。6人次获得国家奖学金。

近年来教学方面的业绩:

主持广西教育科学“十二五”规划2011年度立项课题(No. 2011C0026)1项,负责卓越工程师教育培养计划化学工程领域全日制工程硕士建设。参加化学工程与工艺国家级特色专业、化学化工区级教学团队、广西高等学校特色专业及课程一体化、化学工程与工艺专业教育部“卓越工程师教育培养计划”以及协同创新团队建设发表教改论文9篇,是《现代精细化工生产工艺流程图解》的副主编,参加《大学化学》教材的编写工作,“平台+案例”提升化学化工类研究生创新能力培养的研究与实践荣获广西教学成果奖三等奖(排名第一),地方高校化学化工专业产学研协同育人的研究与实践获广西教学成果奖二等奖(排名第六)

附:代表性科研项目、学术论文、授权专利

(一)在研科研项目

1. 广西协同创新中心团队项目,新型功能材料(GXYSXTZX2016-P2)201605-201904

2. 企业委托项目,稀土材料的合成及工艺研究,201612-201911

3. 广西科技计划项目,新型吡唑酮衍生物及其配合物的合成、结构及性能研究(2015GXNSFAA139031),201509-201808.

4. 桂林市科学技术研究开发项目,新颖氨基-三氮唑衍生物席夫碱配合物的合成、结构及性质研究(20150133-5), 201501-201812.

()发表的部分论文

1.        Hao Chen, Zhi-Gang Gu,* Salma Mirza, Shu-Hua Zhang,* and Jian Zhang,* Hollow Cu-TiO2/C Nanospheres Derived from Encapsulated MOF coating for Efficient Photocatalytic Hydrogen Evolution, Journal of material chemistry A, 2018, http://dx.doi.org/10.1039/C8TA01034J.

2.        Shu hua Zhang, Jiming Wang, Hai-Yang Zhang, Yipeng Fan and Yu Xiao, Highly efficient electroche miluminescence based on 4-amino-1,2,4- Triazole schiff base two-dimensional Zn/Cd coordination polymers, Dalton Transations, 2017, 46, 410-419.

3.        3.Zhehui Weng, Chun Lian Zhang, Hai Yang Zhang, Yanqing Zhou & Shu Hua Zhang, Syntheses, crystal structures, and spectroscopic properties of two new complexes based on 5-hydroxyisophthalic acid, Inorganic and Nano-Metal Chemistry, 2017, 47(3), 390-395.

4.        Hefeng Xu,Xiaodong Fan, Chao Feng& Shuhua Zhang, Synthesis, crystal structure, and Hirschfeld surface analysis of Ni(II) complex [Ni(H1.5bhbm)2(AcO)]·11H2O containing supra-water network, Inorganic and Nano-Metal Chemistry, 2017, 47(3), 423-426.

5.        Hai-Yang Zhang, Wei Wang, Hao Chen, Shu-Hua Zhang,* Yan Li*, Five novel dinuclear copper(II) complexes: Crystal structures, properties, Hirshfeld surface analysis and vitro antitumor activity study, Inorg. Chim. Acta,2016, 453, 507–515.

6.        Ji-Ming Wang, Chong Zhang, Xiu-Qing Zhang & Shu-Hua Zhang*, Solvothermal synthesis and structure of a cubane cobalt cluster with 3,5-dibromo-2-hydroxybenzaldehyde, Inorganic and Nano-Metal Chemistry, 2017, 47(6), 893-896.

7.        ZHANG Hai-Yang XIAO Yu, ZHU Yun, A Novel Copper(II) Complex Based on 4-Amino-1,2,4-triazole Schiff-base: Synthesis, Crystal Structure, Spectral Characterization, and Hirshfeld Surface Analysis, Chinese J. Struct. Chem. 2017, 36(5), 848-855.

8.        Hai-Yang Zhang, Yan Li, Wei Wang, Xiuqing Zhang, Ji-Ming Wang & Shu-Hua Zhang, Tetranuclear nickel(II) clusters: syntheses, crystal structures, magnetic properties and Hirshfeld surface analysis, Journal of Coordination Chemistry, 2016, 69(11-13), 1938-1948.

9.        Zheng-Guang Hu,Ru-Xia Zhao,Shu-Hua Zhang,Song-Ling Chen,Syntheses, Crystal Structure and Property of a Heterometallic Heptanuclear Cluster, J Clust Sci, 2016, 27(6), 1933-1943.

10.     Jiming Wang,Chao Feng,Cheng Min Ge,Shuhua Zhang,Hong Hai,Two New Cubane-Type Tetranuclear Compounds of Copper(II), Nickel(II) Derived from Reduced Schiff Base Ligand: Syntheses, Structures and Magnetic Properties, J Clust Sci, 2016, 27(6), 2001-2011.

11.     Jingling Zhang, Chunlian Zhang, Yu Xiao, Yan Qin, Shuhua Zhang, Two novel trinuclear cluster-based coordination polymers with 2,6-Di-imidazol-1-yl-pyridine: Solvothermal syntheses, crystal structures, properties and Hirshfeld surface analysis, Supramolecular Chemistry, 2016, 28, 3-4, 231-238.

12.     Hua-Hong Zou,* Li Wang, Zhi-Xiang Long, Qi-Pin Qin,* Zhong-Kui Song, Tao Xie, Shu-Hua Zhang,* Yan-Cheng Liu, Bin Lin, Zhen-Feng Chen,* Preparation of 4-([2,2’:6’,2’’-terpyridin]-4’-yl)-N,N-diethylaniline NiII and PtIIcomplexes and exploration of their in vitro cytotoxic activities, European Journal of Medicinal Chemistry, 2016,  108, 1-12.

13.     Shu Hua Zhang, Ru Xia Zhao, Gui Li, Hai Yang Zhang, He Ping Li, Synthesis, Structure, and Luminescent Property of One Zinc (II) Coordination Polymer Constructed from 1H-Benzoimidazole, synthesis and Reactively in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2016, 46(6), 804-808. IF0.518.

14.     RU-XIA ZHAO, JING-LING ZHANG, SHU-HUA ZHANG, and HAI-YANG ZHANGRoom Temperature Synthesis, Crystal Structure, and Properties of a New Heterometallic One-Dimensional Cu-Na PolymerSynthesis and Reactively in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2016, 46(6), 1462-1467. IF0.518.

15.     Qian Jun Deng, Ru Xia Zhao, Jiming Wang, Chen Min Ge, Shu Hua Zhang, Solvothermal Synthesis, Structure and Magnetic Properties of a Novel Heterometallic Cluster with 2-Ethoxy-6-methyliminomethyl-phenol, J Clust Sci, 2016, 27(5), 1645-1653. DOI 10.1007/s10876-016-1030-y.

16.     Xue Ren Huang, Li Yang, Yu-Jie Zhou, Shu-hua Zhang, Hai Yang Zhang, Hong Hai, Two Linear Trinuclear Clusters Based on Schiff Base: Syntheses, Structures and Magnetic Properties, Journal of cluster science 2015, 26(6), 2033-2042.

17.     Zhang, Shu-Hua / Li, Gui / Zhang, Hai-Yang / Li, He-Peng, Microwave-assisted synthesis, structure and property of a spin-glass heptanuclear nickel cluster with 2-iminomethyl-6-methoxy-phenol, Zeitschrift für Kristallographie - Crystalline Materials, 2015, 230(7), 479–484. IF1.310.

18.     Cui Cui Wang,     Hai Ye Li,     Xiao Qiang Zhang,     Yi Min Jiang,     Shu Hua Zhang, Synthesis, Crystal Structure and Magnetic Property of Double μ6-CO32-Centered Nonanuclear Ni(II) Cluster, J. Cluster Sci., 2015, 26(4), 1055-1065. Zhehui Weng, Shu-Hua Zhang, Wei Wang, Jing-Jing Guo, Hong Hai, Syntheses, structures and properties of three new trinuclear nickel clusters with (2-hydroxy-4-methoxyphenyl)-phenyl-methanone,J. Cluster Sci., 2015, 26(4), 1129-1142.

19.     Hong Hai, Hui Wang, Wen Ying Jin, Xiao Dong An, Wen Gang Huang, Shu Hua Zhang*, Synthesis Crystal Structures and Properties of Three Complexes of 5-(pyridin-2-ylmethoxy) isophthalic acid, synthesis and Reactively in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2015, 45(12), 1870-1874.

20.     Li YANG, Jing Jing Guo, Chun Lian Zhang, Shu Hua Zhang* Syntheses, Crystal Structure and Properties of a New Co(II) Coordination Polymer Constructed from 1,10-Phenanthroline, synthesis and Reactive in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2015, 45(8), 1112-1115.

21.     Zhao Ru Xia, Zhang Yi dong, Zhang shu hua*, Zhang hai yang, Li Gui, One dinuclear copper(Ⅱ) complex: synthesis, structure and properties, Molecular Crystals and Liquid Crystals, 2015, 606(1). 147-153.

22.     Ru-Xia Zhao, Shu-Hua Zhang*, Hai-Yang Zhang, Gui Li, Guo-Hua Ding, He-Ping Li* Room Temperature Synthesis, crystal structure and magnetic property of a two-dimensional copper(II) polymer bridged by end-on and end-to-end azide bridges, J. Cluster Sci., 2015, 26(3), 949-958.

23.     Shu-Hua Zhang, Qiu Ping Huang, Hai Yang Zhang, Gui Li, Zheng Liu, Yan Li, Hong liang, Dodecanuclear water cluster in bowl: microwave-assisted synthesis of a heptanuclear cobalt (II) cluster, Journal of Coordination Chemistry, 2014, 67(19), 3155-3166.

24.     Shu-Hua Zhang, Ru-Xia Zhao, Gui Li,Hai-Yang Zhang, Chun-Lian Zhang,  Gilles Muller, Structural Variation from Heterometallic Heptanuclear, Heptanuclear to Cubane Clusters Based on 2-hydroxy-3-ethoxy-benzaldehyde: Effects of pH and Temperature, RSC Adv., 2014, 4, 54837–54846.

25.     Ru-Xia Zhao, Hong Hai, Gui Li, Hai-Yang Zhang, Qiu ping Huang, Shu-Hua Zhang,He-Ping Li, Room temperature syntheses, structures and magnetic properties of two heterometallic tetranuclear clusers, J. Cluster Sci., 2014, 25(6), 1541-1552.

26.     Gui Li, Wei Wang, Shu Hua ZHANG, Hai Yang ZHANG, Fa Yun CHEN, Synthesis, structure and properties of linear trinuclear cobalt cluster with 5-fluoro-2-hydroxy-benzoic acid, J. Cluster Sci., 2014, 25(6), 1589-1597.

27.     Xi-Fu Jiang, Ru-Xia Zhao and Shu-Hua zhang, Crystal structure of aqua-chlorido[2-ethoxyl-6-formylphenolato-k2 O,O'] iron(III) acetonitrile hemisolvate, acta cryst. 2014, E70(11), 269-271.

28.     Shu-Hua Zhang,* Ru-Xia Zhao, Gui Li, Hai-Yang Zhang, Qiu-Ping Huang, Fu-Pei Liang*, Room temperature syntheses, crystal structures and properties of two new heterometallic polymers based on 3-ethoxy-2-hydroxybenzaldehyde ligand, Journal of Solid State Chemistry, 2014, 220, 206–212.

29.     L. Yang, Q. P. Huang, C. L. Zhang, R. X. Zhao, S. H. Zhang, Two disc-like heptanuclear clusters based on Schiff base: syntheses, structure and magnetic properties, Supramol. Chem., 2014, 26(2), 81-87.

30.     X.-Y. Qin, H.-N. Yao, W. Ou, S. H. Zhang, Water Chains in a Novel Copper(II) Compound [Cu(C9H6O4)(C12H8N2)]. 4H2O, Synth. React. Inorg. Met.-Org. Chem., 2014, 44(2), 242-246.

31.     W. Wang, H. Hai, S. H. Zhang,* L. Yang, C. L. Zhang Microwave-Assisted Synthesis, Crystal Structure and Magnetic Behavior of a Schiff Base Heptanuclear Cobalt Cluster,J. Cluster Sci., 2014, 25(2), pp 357-365.

32.     C.-L. Zhang, X. F. Jiang, L. Yang, S. H. Zhang*, S. M. Shi, A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxyl -ethyl) Amino]-Ethanesulfonic Acid: Synthesis and Crystal Structure, J. Cluster Sci.,2014, 25(2),459-466.

33.     Q. P. Huang, G. Li, H. Y. Zhang, S.-H. Zhang*, H. P. Li, Microwave-assisted synthesis, structure and properties of a heptanuclear cobalt cluster with 2-ethyliminomethy-6-methoxy-phenol, Z. Anorg. Allg. Chem., 2014, 640(7), 1403-1407.

34.     Shu-Hua Zhang,* Ru-Xia Zhao, He-Ping Li, Cheng-Min Ge, Gui Li, Qiu-Ping Huang, Hua-Hong Zou, Structural variation from heterometallic cluster-based 1D chain to heterometallic tetranuclear cluster: syntheses, structures and magnetic properties, Journal of solid state chemistry, 2014, 216, 30-35.

35.     Li Yang,Shu-Hua Zhang,* Wei Wang, Jing-Jing Guo, Qiu Ping Huang, Ru-Xia Zhao, Chun-Lian Zhang and Gilles Muller, Ligand Induced Diversification from Tetranuclear to Mononuclear Compounds: Syntheses, Structures and Magnetic properties, Polyhedron, 2014, 74, 49-56.

36.     Ru Xia Zhao, Qiu Ping Huang, Gui Li, Shu Hua zhang,* Hai Yang Zhang, Li Yang,* Synthesis and Crystal Structure of an Oxo Bridged Disc-like Heptanuclear Co(II) Cluster with Unconventional Nona-Hydrogen Bonds, J. Cluster Sci., 2014, 25(4), 1099-1108.

37.     HUANG Qiu-Ping, LI Gui, ZHANG Shu-Hua, ZHANG Hai-Yang, A new tetranuclear cobalt cluster with 1H-Benzimidazol-methanol]: synthesis and crystal structure, Chin. J. Struct. Chem., 2014, 33(8), 1135-1140.

38.     Qiu Ping Huang, Shu Hua Zhang,*Hai Yang Zhang, Gui Li, Mei Chun Wu,Microwave–assisted synthesis, structure and properties of an nano-double-bowl-like heptanuclear nickel(II) cluster, J. Cluster Sci., 2014, 25(5),1489-1499.

39.     S.-H. Zhang,* Y. D. Zhang, H. H. Zou, J. J. Guo, H. P. Li, Y. Song, H. Liang, A family of cubane cobalt and nickel clusters: Syntheses, structures and magnetic properties, Inorg. Chim. Acta, 2013, 396, 119–125.

40.     J.-J. Guo, W. Wang, Y. D. Zhang, Yang Li, S. H. Zhang,* X. Q. Zhang, Solvothermal syntheses and structures of three clusters based on (1H- benzoimidazol-2-yl)-methanethiol, J. Coord. Chem., 2013, 66(8), 1467-1476.

41.     Y.-D. Zhang, S. H. Zhang,* C. M. Ge, Y. G. Wang, Y. H. Huang, H. P. Li, Synthesis and Crystal Structures of Two Heterobinuclear Nickel Polymers [NiNaL(dca)]nand [NiNaL(dca)]2n·(CH3COOCH3)n·(H2O)n,Synth. React. Inorg. Met.-Org. Chem., 2013, 43(8), 990-994.

42.     Y. Xiao, Q. S. Gong, Z. Q. Li, J. J. Guo, C. Feng, S. H. Zhang,* Di-Radical dinuclear copper complex: Synthesis, structure and magnetic properties, Synthesis, structure and magnetic properties, J. Coord. Chem., 2013, 66(11), 2004-2011.

43.     X.-Y. Qin, J. L. Zeng,S. H. Zhang, Y. M. Jiang, Synthesis and Crystal Structure of Schiff Base Compound Zn(C10H9NO5S)(C12H8N2)(H2O)]·4.25H2O,Synth. React. Inorg. Met.-Org. Chem.and Nano-Met.Chem., 2012, 42, 915–919.

44.     F.-Y. Chen, S. H. Zhang,* H. P. Li, L. J. Zhang, Y. D. Zhang, Solvothermal synthesis, crystal structure and magnetic behavior of a Schiff base heterometallic cluster, J. Mol. Struct., 2011, 1006, 142–146.

45.     S.-H. Zhang,* N. Li, C. M. Ge, C. Feng, L. F. Ma, Structures and magnetism of {Ni2Na2}, {Ni4} and {Ni6IINiIII}2-hydroxy-3-alkoxy-benzaldehyde clusters, Dalton Trans., 2011, 40, 3000-3007.

46.     Y. Xiao, S. H. Zhang,* G. Z. Li, Y. G. Wang, C. Feng, Synthesis, crystal structure and magnetic properties of cubane and linear trinuclear nickel complexes formed by 3,5-dichloro-2-hydroxybenzylaminoacetic acid, Inorg. Chim. Acta., 2011, 366, 39-43.

47.     C.-M. Ge, S. H. Zhang,* C. Feng, Y. G. Wang, W. Li, Heterotetranuclear Metal Complex {Ni2Na2} by Azido-bridged, Z. Anorg. Allg. Chem. ,2011, 637, 112–116.

48.     H.-H. Zou, S. H. Zhang,* Y. Xiao, C. Feng, Y. G. Wang, Solvothermal synthesis and structures of three novel heterometallic microporous coordination polymers assembled from 2-hydroxy-nicotinic acid, Struct. Chem., 2011, 22, 135–140.

49.     S.-H. Zhang, L. F. Ma, H. H. Zou, Y. G. Wang, H. Liang, Anion Induced Diversification from Heptanuclear to Tetranuclear Clusters: Syntheses, Structures and Magnetic Properties, Dalton Trans., 2011, 40, 11402-11409.

50.     Y. Xiao, Y. Hu, S. H. Zhang,* B. Zhang, X. Y. Peng, Z. Q. Li, Microwave- Assisted Synthesis of a 1-D Water Chain in a Mononuclear Nickel Complex [Ni(bimp)2]·2H2O, Where Hbimp is a 4-Bromo-2-iminomethyl-6-methoxyphenol, Synth. React. Inorg. Met.-Org. Chem., 2011, 41, 1203–1207.

51.     X. J. Ying. S. H. Zhang,* X. H. Zhou, J. L. Zuo, A Mn(II) Coordination Polymer with the Flexible Tripodal Ligand 1,3,5-Tris-(imidazol-1-ylmethyl) benzene, Chin. J. Sruct. Chem., 2010, 29(2), 302-306.

52.     S. H. Zhang,* C. Feng, Microwave-assisted synthesis, crystal structure and fluorescence of novel coordination complexes with Schiff base ligands, J. Mol. Struct., 2010, 977, 62–66.

53.     S. H. Zhang,* Y. G. Wang, C. Feng, G. Z. Li, Dinuclear copper (II) complex and 1D copper (II) Complex with taurine schiff base: synthesis, crystal structure and properties, J. Coord. Chem., 2010, 63(21), 3697-3705.

54.     S.-H. Zhang, Y. Song, H. Liang, M. H. Zeng, Microwave-assisted synthesis, crystal structure and properties of a disc-like heptanuclear Co(II) cluster and a heterometallic cubanic Co(II) cluster, CrystEngComm, 2009, 11, 865–872(SCI收录).

55.     S. H. Zhang,* M. F. Tang, C. M. Ge, Microwave Synthesis, Crystal Structure and Magnetic Behavior of a Schiff Base Trinuclear Nickel Cluster, Z. Anorg. Allg. Chem., 2009, 635, 1442-1446.

56.     S. H. Zhang,* Z. J. Jin, H. H. Zou, F. Zhong, C. M. Ge, Solvothermal synthesis and structure of [Co(5-NH2-bdc)(4,4′-dpdo)(H2O)]ncomplex (4,4′-dpdo = 4,4′- bipyridrl-N,N′-dioxide, 5-NH2-bdc = 5-aminoisophth-alic acid), Chin. J. Sruct. Chem.,2009, 28(12), 630~1634.

57.     F.-Y. Chen, S. H. Zhang,* G. Z. Li, C. M. Ge, Synthesis, structure and properties of a binuclear copper complex [Cu(Br2hama)(DMF)]2, where Br2hamaH2= [(3,5- Dibromo-2-hydroxy-benzylidene)-amino]–methane-sulfonic acid, Chin. J. Sruct. Chem., 2009, 28(8), 921-928.

58.     X.-Y. Qin, S. H. Zhang,* Y. M. Jiang, J. C. Liu, J. H. Qin, Syntheses, crystal structures and antibacterial activities of [Cu2(C11H11NO5S)2(H2O)4]·5H2O and [Ni2(C11H11NO5S)2 (H2O)4]·2H2O, J. Coord. Chem., 2009, 62(3), 427–439.

59.     S. H. Zhang, Y. L. Zhou, X. J. Sun, L. Q. Wei, M. H. Zeng, H. Liang, Heterometallic clusters arising from cubic Ni3M'O4 (M' = K and Na) entity: Solvothermal synthesis with/without the assistance of microwave, J. Solid State Chem.,2009,182,2991-2996.

(三)获得的授权专利

1.一种单分子磁体[Co4(hmb)43-OMe)4(MeOH)4]的制备方法,专利号:ZL201110287083.3,申请人:张淑华、肖瑜、郭晶晶、张义东、王寅光、刘峥,发文日期2014.01.08.

2. 3,5-二溴水杨醛缩水合肼双希夫碱的原位合成方法;专利号:ZL201210503841.5,申请人:张淑华、杨莉,发文日2015.03.05发文序号:2014110501019990

3.荧光材料[ZnNa(ehbd)2N3]2及合成方法,专利号:ZL201410292786.9,申请人:张淑华、赵儒霞,发文日期:2015928

4.一种[Cu2(L3)2]的原位合成方法;专利号:ZL201310281414.1 申请人:张淑华、黄秋萍、肖瑜、赵儒霞,发文序号:2015092800934610,发文日期:20151021

5.一种[Cu2(L2)2](C2H3N)2的原位合成方法;申请专利号:ZL201310281430.0 申请人:张淑华、黄秋萍、肖瑜、张春练,发文序号:2015092800970630,发文日期:2015.10.26

6.3,5-二溴水杨酸吖嗪双希夫碱铜配合物的原位合成方法, 专利号ZL201310210623.7,申请人:张淑华杨莉肖瑜张春练;发文序号:2015120400379160,发文日期:2016.02.05

7.具抗癌活性的3,5-二溴水杨醛缩2-氨基-2-甲基-1,3-丙二醇希夫碱的合成及应用,专利号:ZL201410829304.9,申请人:张淑华、李桂、陈林波,发文序号:2015110900184320,发文日期:2016.02.26

8.一种[Mn(L)(AcO)]·(HAc)的原位合成方法;专利号:ZL201310301196.3, 申请人:张淑华、黄秋萍、肖瑜、赵儒霞,发文序号:2016032400394130,发文日期:2016.04.05

9.荧光材料[CuNa(ehbd)2(dca)(CH3OH)]及合成方法,专利号:ZL201410418048.4, 申请人:张淑华,赵儒霞、周玉洁、张海洋, ZL201410418048.4, 发文序号:2016030300406980,发文日期:2016.04.07

10.[Ni(L)(AcO)(H2O)2](C2H3N)的原位合成方法,专利号:ZL201310234398.0发文序号2016011901299010,发文日期2016.04.11张淑华黄秋萍肖瑜王娓

11.5-溴水杨醛缩水合肼双希夫碱的抑菌和抗癌的应用,专利号:ZL201410414182.7,申请人:张淑华、杨莉, 发文序号:2016042400410270,发文日期:2016.05.10.

12.磁性材料[Co2Na2(hmb)4(N3)2(CH3CN)2]·(CH3CN)2及合成方法,申请专利号:ZL201410292859.4,申请人:张淑华、赵儒霞、周玉洁,发文序号:2016050401178920,发文日期:2016.05.13

13.具抗癌活性的配合物[Zn(H2L4)2]·(H2O)的合成及应用,申请人:张淑华、李桂、陈林波、张海洋。专利号:ZL201510071712.7.发文序号:2016042724040,发文日期:2016519日。

14.一种配合物[Cu2(L7)(L10)]的原位合成及作为抗癌药物的应用,专利号:ZL201410800284.2,发文序号:2016051000352110,发文日期:2016520日。申请人:肖瑜、黄秋萍、张淑华.

15.荧光材料Zn2(hfoac)4(4,4-pybi)2及合成方法,专利号:ZL201410418042.7, 申请人:张淑华、赵儒霞、王娓、陈宁,发文序号201605090040285020160524日。

16.磁性材料HN(C2H5)3·[Co4Na3(heb)6(N3)6]及合成方法,专利号:ZL201410292855.6,申请人:张淑华、赵儒霞、周玉洁发文序号:2016052401484740,发文日期:20160621日。

17.荧光材料Zn(hfoac)2(phen)H2O及合成方法,专利号:ZL201410454852.8,申请人:周玉洁、赵儒霞、张淑华、王娓;发文序号:2016042500699370,发文日期:20160627日。

18.荧光材料Zn2(hfoac)4(phen)2及合成方法,专利号:ZL201410455028.4,申请人:肖瑜、赵儒霞、王娓、陈林波、张淑华, 发文序号:2016042500359910,发文日期:20160629日。

19.[Ni(L1)(L2)]·(H2O)3的原位合成方法;专利号:ZL201310297610.8 申请人:张淑华、黄秋萍、肖瑜、张春练,发文序号:201607200239580,发文日期:201688日。

20.磁性材料[Cu3(N3)6(DMF)2]n及合成方法,专利号:ZL201410292754.9,申请人:肖瑜、赵儒霞、张淑华,发文序号:2016072801446640,发文日期:2016817日。

21.具抗癌活性的3,5二氯水杨醛缩2-氨基-2-甲基-1,3-丙二醇希夫碱的合成及应用,专利号:ZL201410830039.6,申请人:张淑华、李桂、陈林波,发文序号:2016062900535220,发文日期:2016818日。

22.磁性材料[Ni2Na2(hmb)4(N3)2(CH3CN)2]·(CH3CN)2及合成方法,专利号:ZL201410292900.8,申请人:张淑华、赵儒霞、肖瑜,发文序号:20160081501382230,发文日期:2016824日。

23.磁性材料HN(C2H5)3·[Ni4Na3(heb)6(N3)6]及合成方法,申请专利号:201410292880.4,申请人:张淑华、赵儒霞、陈林波,发文序号2017090600392050,发文日期:2017.09.15

24.磁性材料[Cu3Na2(ehbd)2(N3)6]n及合成方法,申请专利号:ZL20140292870.0,申请人:赵儒霞、张淑华、陈宁 ,授权日期:2017828日。

25. 张淑华、张海洋、肖瑜,发光材料[Mn(tidc)2]n及合成方法,ZL201610171182.8, 授权日期:20171107.已转让中铝广西有色稀土开发有限公司

26.张淑华、 张海洋、肖瑜,发光材料[Zn(tibc)2]n及合成方法,ZL201610171237.5, 授权日期:2017116号。

27.张淑华,张海洋,肖瑜,发光材料[Cd (tidc)2]n及合成方法,ZL201610171128.3, 授权日期:20171117号。

28.张淑华、 张海洋、 肖瑜,发光材料[Mn(tibc)2]n及合成方法,ZL201610171214.4 授权日期:20171117号。

29.张淑华、张海洋、肖瑜,发光材料[Cd(tibc)2]n及合成方法,ZL201610171264.2,授权日期:20171120号。已转让中铝广西有色稀土开发有限公司

 

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